TEA-Stearate
Synonyms
Octadecanoic acid, compd. with 2,2',2''-nitrilotris(ethanol) (1:1);
Stearic acid, compound with 2,2',2''-nitrilotriethanol (1:1);
Triethanolamine stearate;
Category
Anionic Surfactant
> Carboxylate
>> Chain Carboxylate
>>> Alkyl Carboxylate
>>>> Linear Alkyl Carboxylate
Chemical Numbering System
CAS: 4568-28-9
EINECS: 224-945-5
Molecular Formula & Molecular Weight
Molecular Formula: C24H51NO5; C18H36O2.C6H15N1O3
Molecular Weight: 433.67
Structure
Properties
Appearance (1), solid.
Solubility dispersible in water.
Stability stable.
Risk Solid form: flammable material; irritation, irritation to skin, eye, respiratory system. Harmful products of combustion are CO, CO2 and so on. Contact with strong oxidants, can cause to burn.
GHS label:
Ecology may be hazardous to environment. Water body should be given special attention.
Biodegradability biodegradable.
Characteristics excellent cleansing, emulsifying, dispersing, lubricating, foaming, solubilizing abilities.
Note (1), Should not be used in children products that can be direct prolonged contact with the skin, such as skin care products.
(2), Avoid using in children cleaning products, such as shampoos.
(3), Do not use in nitrosating environment. Reaction of triethanolamine and nitrous acid can not produce nitrosamines, however, reaction of contained secondary amine of triethanolamine and nitrous acid can produce nitrosamines. Nitrosamine is a carcinogen.
Synthesis
Quality Standards & Test Methods
1, Physical and chemical indexes
Item |
Physical and chemical indexes |
Solid |
|
Actives, %, ≥ |
95.0 |
Test Methods
(1), Actives
GB/T 13173 Surface active agents -- Detergents -- Testing methods
GB/T 5173 Surface active agents and detergents -- Determination of anionic-active matter by direct two-phase titration procedure
ISO 2271 Surface active agents -- Detergents -- Determination of anionic-active matter by manual or mechanical direct two-phase titration procedure
2, Hazardous substances indexes
Item |
Hazardous substances indexes |
Solid |
|
Heavy metals (as Pb), mg/kg, ≤ |
20 |
As, mg/kg, ≤ |
3 |
Test Methods
(1), Heavy metals (as Pb)
Safety and Technical Standards for Cosmetics (2015 Edition)
GB/T 30799 The test method of food detergents -- Determination of heavy metals
(2), As
Safety and Technical Standards for Cosmetics (2015 Edition)
GB/T 30797 The test method of food detergents -- Determination of total arsenic
3, Further explanation
(a), On physical and chemical indexes: firstly, shall be indicated carbon atom distribution; secondly, shall be indicated average molecular weight.
(b), Used in cosmetics, should be test for harmful substances; or furtherly test for microorganisms.
Major Uses
1, Typical applications
Use as cleansing agent.
Use as emulsifying agent, dispersing agent.
Use as lubricant.
2, Personal care products
Cleansing agent, emulsifying agent in personal care products.
* * * * * *
Further information:
(1), In accordance with EU regulations (EC) No 1223/2009, directive 2003/83/EC, triethanolamine and its salts are included in Annex III/62.
Can be applied to leave-on products and rinse-off products.
Maximum concentration is 2.5% in leave-on products (as triethanolamine).
In raw materials, maximum secondary amine content is 0.5%.
Maximum nitrosamine content is 50μg/kg.
The container is nitrite-free.
(2), In accordance with Safety and Technical Standards for Cosmetics (2015 Edition) of China, triethanolamine and its salts are the restricted components.
Can be applied to leave-on products and rinse-off products.
Maximum concentration is 2.5% in leave-on products (as triethanolamine).
In raw materials, maximum secondary amine content is 0.5%.
Maximum nitrosamine content is 50μg/kg.
The container is nitrite-free.
Manufacturers
Update: 20130817(1); 20180826(2);