TEA-Oleyl Sulfate
Synonyms
(9Z)-Octadecenyl hydrogen sulfate, compound with 2,2',2''-nitrilotrisethanol (1:1);
Category
Anionic Surfactant
> Sulfate
>> Chain Alcohol Sulfate
>>> Alkenol Sulfate
>>>> Linear Enol Sulfate
Chemical Numbering System
CAS: N/A
EINECS: N/A
Molecular Formula & Molecular Weight
Molecular Formula: C24H51NO7S; C18H36O4S.C6H15N1O3
Molecular Weight: 497.73
Structure
Properties
Appearance (1), liquid.
Odor faint characteristic odor.
Solubility soluble in water.
Stability stable in alkali, weak acid and hard water; unstable in strong acid, hydrolyzed, reduced to alcohol. Easily oxidized.
Risk Liquid form: irritation, irritation to skin, eye.
GHS label: 
Ecology may be hazardous to environment. Water body should be given special attention.
Biodegradability biodegradable.
Characteristics excellent cleansing, foaming, emulsifying, wetting, permeating, dispersing, solubilizing, lubricating abilities. Mild. Resistant to hard water. Transparent at low temperature.
Note (1), Should not be used in children products that can be direct prolonged contact with the skin, such as: skin care products.
(2), Avoid using in children cleaning products, such as: shampoos.
(3), Compare with triethanolamine, diethanolamine and monoethanolamine have higher toxicity, and therefore diethanolamine oleyl sulfate and monoethanolamine oleyl sulfate are not suitable for personal care products, also run low in other applications.
(4), Do not use in nitrosating environment. Reaction of triethanolamine and nitrous acid can not produce nitrosamines, however, reaction of contained secondary amine of triethanolamine and nitrous acid can produce nitrosamines. Nitrosamine is a carcinogen.
Synthesis
Currently, sulfated reaction through continuous reactor (such as: falling film reactor) is the most widely used method for preparing sulfates.
Generally, oleyl alcohol and sulfur trioxide react through reactor, then triethanolamine neutralizes, finally obtain product.
US patent 8,921,588 (Process for preparing sulfates and/or sulfonates in a micro-reaction system) presents a synthetic process. Conditions: mole ratio of sulfur trioxide and alcohols or other raw materials: 1:1; temperature: 30-60°C; reactor: falling film reactor.
Quality Standards & Test Methods
1, Physical and chemical indexes
|
Item |
Physical and chemical indexes |
|
Liquid |
|
|
Actives, %, ≥ |
30.0 |
Test Methods
(1), Actives
GB/T 5173 Surface active agents and detergents -- Determination of anionic-active matter by direct two-phase titration procedure
ISO 2271 Surface active agents -- Detergents -- Determination of anionic-active matter by manual or mechanical direct two-phase titration procedure
2, Hazardous substances indexes
|
Item |
Hazardous substances indexes |
|
Liquid |
|
|
Heavy metals (as Pb), mg/kg, ≤ |
20 |
|
As, mg/kg, ≤ |
3 |
Test Methods
(1), Heavy metals (as Pb)
Safety and Technical Standards for Cosmetics (2015 Edition)
GB/T 30799 The test method of food detergents -- Determination of heavy metals
(2), As
Safety and Technical Standards for Cosmetics (2015 Edition)
GB/T 30797 The test method of food detergents -- Determination of total arsenic
3, Further explanation
(a), On physical and chemical indexes: firstly, shall be indicated carbon atom distribution; secondly, shall be indicated average molecular weight.
Major Uses
1, Typical applications
Use as cleansing agent.
Use as foaming agent.
Use as emulsifying agent, dispersing agent.
2, Personal care products
Cleansing agent, foaming agent, emulsifying agent in personal care products.
For example, main ingredient or auxiliary ingredient for cleansing agent, foaming agent in shampoo, hand sanitizer, bubble bath, shaving foam and other products.
Particularly suitable for washing dry hair.
* * * * * *
Further information:
(1), In accordance with EU regulations (EC) No 1223/2009, directive 2003/83/EC, TEA-oleyl sulfate is included in Annex III/62.
TEA-oleyl sulfate can be applied to leave-on products and rinse-off products.
Maximum concentration of TEA-oleyl sulfate is 2.5% in leave-on products (triethanolamine calculated).
In raw materials, maximum secondary amine content is 0.5%.
Maximum nitrosamine content is 50μg/kg.
The container is nitrite-free.
3, Household detergents
Main ingredient or auxiliary ingredient for cleansing agent, foaming agent in laundry detergent, carpet cleaning agent, kitchen cleaning agent and other household products.
4, Industrial cleaning agents
Main ingredient or auxiliary ingredient for cleansing agent, foaming agent.
5, Pets
Main ingredient or auxiliary ingredient for cleansing agent, foaming agent in shampoos and other pet products.
6, Textile, leather
Use as emulsifier, foaming agent, cleansing agent, wetting agent, antistatic agent, solubilizing agent.
Manufacturers
Update: 20131018(1); 20161009(2);