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Dodecanoic Acid

Time: 2012-10-03 16:06:58; Count: 26

Dodecanoic Acid

Synonyms

Lauric acid;

n-Dodecanoic acid;

1-Undecanecarboxylic acid;

Category

Anionic Surfactant

> Carboxylate

>> Chain Carboxylate

>>> Alkyl Carboxylate

>>>> Linear Alkyl Carboxylate

Chemical Numbering System

CAS: 143-07-7

EINECS: 205-582-1

Molecular Formula & Molecular Weight

Molecular Formula: C12H24O2

Molecular Weight: 200.32

Structure

Properties

Appearance    (1), white solid.

Solubility    insoluble in water. soluble in ethanol.

Physical - chemical properties

Water solubility, mg/L

4.81 (25°C)[1]

Melting point, °C

43.8[1]

Stability    stable.

Risk    Solid form: flammable material; irritation, irritation to skin, eye, respiratory system. Harmful products of combustion are CO, CO2 and so on. Contact with strong oxidants, can cause to burn.

GHS label:  

Animal Toxicity

Table 1 Animal toxicity values

rat oral LD50

12000mg/kg[2]

mouse intravenous LD50

131mg/kg[2]

Ecology    may be hazardous to environment. Water body should be given special attention.

Biodegradability    biodegradable.

Characteristics    excellent cleansing, emulsifying, dispersing, solubilizing, foaming abilities. Nonresistant to hard water.

Synthesis

(1), The crude fatty acids are obtained by saponifying hydrolysis reaction of fats (for example: coconut oil or palm-kernel oil).

(2), Crude fatty acids are washed, distilled and decolored, then obtain finished product.

Quality Standards & Test Methods

1, Physical and chemical indexes

Item

Physical and chemical indexes

Solid

Actives, %, ≥

95.0

Test Methods

(1), Actives

GB/T 13173 Surface active agents -- Detergents -- Testing methods

GB/T 5173 Surface active agents and detergents -- Determination of anionic-active matter by direct two-phase titration procedure

ISO 2271 Surface active agents -- Detergents -- Determination of anionic-active matter by manual or mechanical direct two-phase titration procedure

2, Hazardous substances indexes

Item

Hazardous substances indexes

Solid

Heavy metals (as Pb), mg/kg, ≤

20

As, mg/kg, ≤

3

Test Methods

(1), Heavy metals (as Pb)

Safety and Technical Standards for Cosmetics (2015 Edition)

GB/T 30799 The test method of food detergents -- Determination of heavy metals

(2), As

Safety and Technical Standards for Cosmetics (2015 Edition)

GB/T 30797 The test method of food detergents -- Determination of total arsenic

3, Product standards

(1), Chinese standards

(1a), GB 1886.81 Food safety national standard -- Food additive -- Lauric acid

4, Further explanation

(a), On physical and chemical indexes: firstly, shall be indicated carbon atom distribution; secondly, shall be indicated average molecular weight.

(b), Used in cosmetics, should be test for harmful substances; or furtherly test for microorganisms.

Major Uses

1, Typical applications

Use as cleansing agent.

Use as emulsifying agent, dispersing agent.

2, Household detergents

Use as cleansing agent. For example: laundry detergent.

3, Personal care products

Cleansing agent, emulsifying agent in personal care products.

4, Machinery industry

Lubricant in metal processing, powder molding.

5, Food

Food additive (perfume), processing aids in food industry.

6, Organic synthesis

Widely used in preparation of lauric acid esters. Lauric acid esters can be used in personal care products, food, medicine, etc.

Widely used in preparation of lauric acid salts. Lauric acid salts can be used in personal care products, household cleaning products, fabricated metal products, plastic products, etc.

7, Pets

Use as cleansing agent, emulsifying agent.

Manufacturers

 

References

[1]: HSDB. 143-07-7, Dodecanoic acid

[2]: ChemIDplus. 143-07-7, Dodecanoic acid

Update: 20131102(1); 20180106(2);

Article

[Terminology] Dispersion system

[Terminology] Vesicle

Pandect of Ester surfactants (1): Definition

[Terminology] Van Der Waals force

[Terminology] Micellar aggregation number

Standard

Test methods of surfactants, catalog, Chinese national standards

Surfactants, catalog, Chinese national standards