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Zinc Stearate

Time: 2012-10-01 16:13:53; Count: 147

Zinc Stearate

Synonyms

Stearic acid, zinc salt;

Octadecanoic acid, zinc salt;

Zinc octadecanoate;

Zinc dioctadecanoate;

Category

Anionic Surfactant

> Carboxylate

>> Chain Carboxylate

>>> Alkyl Carboxylate

>>>> Linear Alkyl Carboxylate

Chemical Numbering System

CAS: 557-05-1

EINECS: 209-151-9

Molecular Formula & Molecular Weight

Molecular Formula: C36H70ZnO4; C36H72O4.Zn

Molecular Weight: 632.35

Structure

Properties

Appearance    (1), white powder.

Solubility    insoluble in water. soluble in benzene.

Physical - chemical properties

Melting point, °C

130[1]

Stability    stable.

Risk    Solid form: flammable material; irritation, irritation to skin, eye, respiratory system. Harmful products of combustion are CO, CO2 and so on. Contact with strong oxidants, can cause to burn.

GHS label:  

Animal Toxicity

Table 1 Animal toxicity values

rat oral LD50

> 10000mg/kg[2]

rat intratracheal LDLo

250mg/kg[2]

mouse oral LD50

> 10000mg/kg[2]

mouse intraperitoneal LD50

354mg/kg[2]

Ecology    may be hazardous to environment. Water body should be given special attention.

Biodegradability    biodegradable.

Characteristics    excellent lubricating, emulsifying, dispersing abilities.

Note    (1), Do not used in children products, such as: talcum powder.

Synthesis

Sodium stearate reacts with zinc sulfate solution, then obtain.

Quality Standards & Test Methods

1, Physical and chemical indexes

Item

Physical and chemical indexes

Solid

Actives, %, ≥

95.0

Zn, %

 

Test Methods

(1), Actives

GB/T 13173 Surface active agents -- Detergents -- Testing methods

GB/T 5173 Surface active agents and detergents -- Determination of anionic-active matter by direct two-phase titration procedure

ISO 2271 Surface active agents -- Detergents -- Determination of anionic-active matter by manual or mechanical direct two-phase titration procedure

(2), Zn

 

2, Hazardous substances indexes

Item

Hazardous substances indexes

Solid

Heavy metals (as Pb, except Zn), mg/kg, ≤

20

As, mg/kg, ≤

3

Test Methods

(1), Heavy metals (as Pb)

Safety and Technical Standards for Cosmetics (2015 Edition)

GB/T 30799 The test method of food detergents -- Determination of heavy metals

(2), As

Safety and Technical Standards for Cosmetics (2015 Edition)

GB/T 30797 The test method of food detergents -- Determination of total arsenic

3, Product standards

(1), Chinese standards

(1a), Chinese Pharmacopoeia (2015 Edition) Zinc stearate

(1b), HG/T 3667 Zinc stearate

4, Further explanation

(a), On physical and chemical indexes: firstly, shall be indicated carbon atom distribution; secondly, shall be indicated average molecular weight.

(b), Used in cosmetics, should be test for harmful substances; or furtherly test for microorganisms.

Major Uses

1, Typical applications

Use as lubricant.

Use as emulsifying agent, dispersing agent.

2, Household detergents

Use as lubricant, release agent.

3, Personal care products

Anticaking agent, colorant, humectant in personal care products.

4, Machinery industry

Lubricant, release agent, glidant in metal processing.

5, Rubber industry

Vulcanization active agent, softener in rubber.

6, Plastics

Lubricant, releasing agent used in manufacture of styrene resin, phenol resin, amino resins.

7, Pets

Use as anticaking agent, colorant.

8, Powder forming

Lubricant, release agent, glidant in powder forming.

9, Coatings

Used in waterborne coatings. Can increase the smoothness.

10, Medicine

Pharmaceutical excipients. Use as lubricant, such as lubricant for tablets and capsules. (This section is for reference only, should be implemented according to local Pharmacopoeia.)

Manufacturers

 

References

[1]: HSDB. 557-05-1, Zinc stearate

[2]: ChemIDplus. 557-05-1, Zinc stearate

Update: 20131102(1); 20171215(2);

Article

[Terminology] Dispersion system

[Terminology] Vesicle

Pandect of Ester surfactants (1): Definition

[Terminology] Van Der Waals force

[Terminology] Micellar aggregation number

Standard

Test methods of surfactants, catalog, Chinese national standards

Surfactants, catalog, Chinese national standards