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Sodium Ricinoleic Acid n-Butyl Ester Sulfate

Time: 2012-09-26 16:01:31; Count: 43

Sodium Ricinoleic Acid n-Butyl Ester Sulfate

Synonyms

Sodium Ricinoleic Acid Butyl Ester Sulfate;

Category

Anionic Surfactant

> Sulfate

>> Ester-based Sulfate

>>> Natural Products Ester Derivatives Sulfate

>>>> Fatty Acid (Plant Origin) Ester Derivatives Sulfate

Chemical Numbering System

CAS: N/A

EINECS: N/A

Molecular Formula & Molecular Weight

Molecular Formula: N/A

Molecular Weight: N/A

Structure

Schematic formula of basic component:

Properties

Appearance    (1), yellow or brown viscous liquid; (2), solid.

Solubility    soluble in water.

Stability    stable in weak alkali, weak acid and hard water; unstable in strong acid, strong alkali. Resistant to hard water and acid more than turky red oil.

Risk    Solid form: flammable material; irritation, irritation to skin, eye, respiratory. Harmful products of combustion are CO, CO2 and so on. Contact with strong oxidants, can cause to burn.

GHS label:  

Liquid form: irritation, irritation to skin, eye.

GHS label: 

Ecology    may be hazardous to environment. Water body should be given special attention.

Biodegradability    biodegradable.

Characteristics    excellent emulsifying, wetting, permeating, dispersing, solubilizing abilities. Resistant to hard water. Low foaming.

Note    (1), Avoid using in children cleaning products, such as shower gels, shampoo, skin care products.

Synthesis

Possible synthetic method A:

(1), Castor oil fatty acid is obtained by hydrolysis of castor oil;

(2), Ricinoleic acid butyl ester is obtained by esterification of castor oil fatty acid and butanol;

(3), Ricinoleic acid butyl ester sulfate is obtained by sulfation of ricinoleic acid butyl ester and concentrated sulfuric acid (or sulfur trioxide);

(4), Sodium ricinoleic acid butyl ester sulfate is obtained by water cleaning, neutralization.

Quality Standards & Test Methods

1, Physical and chemical indexes

Item

Physical and chemical indexes

Liquid

Actives, %, ≥

30

pH (25°C, 1% solution)

6.5 - 9.5

Test Methods

(1), Actives

GB/T 5173 Surface active agents and detergents -- Determination of anionic-active matter by direct two-phase titration procedure

ISO 2271 Surface active agents -- Detergents -- Determination of anionic-active matter by manual or mechanical direct two-phase titration procedure

(2), pH

GB/T 6368 Surface active agents -- Determination of pH of aqueous solution - Potentiometric method

ISO 4316 Surface active agents -- Determination of pH of aqueous solutions -- Potentiometric method

2, Hazardous substances indexes

Item

Hazardous substances indexes

Solid

Liquid

Heavy metals (as Pb), mg/kg, ≤

20

20

As, mg/kg, ≤

3

3

Test Methods

(1), Heavy metals (as Pb)

Safety and Technical Standards for Cosmetics (2015 Edition)

GB/T 30799 The test method of food detergents -- Determination of heavy metals

(2), As

Safety and Technical Standards for Cosmetics (2015 Edition)

GB/T 30797 The test method of food detergents -- Determination of total arsenic

3, Further explanation

(a), On physical and chemical indexes: firstly, shall be indicated carbon atom distribution; secondly, shall be indicated average molecular weight.

Major Uses

1, Typical applications

Widely use as emulsifying agent. Such as: pesticides, metal working fluids, emulsion polymerization, and other fields.

Use as wetting agent, permeating agent.

2, Textile

Penetrating agent, softening agent, leveling agent in textile.

3, Leather

Penetrating agent, fat-liquoring agent, retanning agent in leather.

4, Emulsion polymerization

Emulsifier, particle size controlling agent in emulsion polymerization.

Manufacturers

 

Update: 20131018(1); 20160829(2);

Article

[Terminology] Dispersion system

[Terminology] Vesicle

Pandect of Ester surfactants (1): Definition

[Terminology] Van Der Waals force

[Terminology] Micellar aggregation number

Standard

Test methods of surfactants, catalog, Chinese national standards

Surfactants, catalog, Chinese national standards